That 25% is peak efficiency. It does not take into account:
(1) the temperature of the panel (higher temp->lower efficiency), hence the need for passive cooling of the panels in space due to a lack of working fluid (air).
(2) the angle of the incidence: both angles have to be 'perfect' for that 25% to happen, which in practice puts all kinds of constraints on orientation, especially when coupled with requirements placed on the rest of the satellite.
(3) the effects of aging (which can be considerable, especially in space), for instance, due to solar wind particles, thermal cycling and so on
(4) the effect of defects in the panels causing local failure that can cascade across strings of cells and even strings of panels
(5) the effects of the backing and the glass
(6) in space: the damage over time due to mechanical effects of micro meteorite impact on cells and cover; these can affect the panels both mechanically and electrically
To minimize all of these effects (which affect both operational life span of panels as well as momentary yield) and effectively to pretend they do not exist is proof that you are clueless, and yet you make these (loud) proclamations. Gell-Mann had something to say about this, so now your other contributions suffer from de-rating.
2) pointing the panels straight at the sun for a sun-synchronous orbit is not exactly unobtainium technology
3) through 6) agreed, these issues need to be taken into account but I don't see how that meaningfully invalidates my claim that a solar panel operated at 25% efficiency turns ballpark ~75% of incident photons into heat. Thats basic thermodynamics.