On the SEU issue I’ll add in that even in LEO you can still get SEUs - the ISS is in LEO and gets SEUs on occasion. There’s also the South Atlantic Anomaly where spacecraft in LEO see a higher number of SEUs.
The fact that people aren’t using something isn’t evidence that it’s not possible or even a great idea, it could be that a practical application didn’t exist before or someone enterprising enough hasn’t come along yet.
Radiative cooling is great for achieving temperature a bit below ambient at night when you don’t have any modern refrigeration equipment. That’s about all. It’s used in space applications because it’s literally the only option.