In time O(n) you can use O(n) cells on a tape, but there are O(2^n) possible configurations of symbols on a tape of length n (for an alphabet with 2 symbols), so you can do so much more with n space than with n time.
More precisely, I think it is intuitive that the class of problems that can be solved in any time given O(n) space is far larger than the class of problems that can be solved in any space given O(n) time.
If your program uses O(n) memory, it must run at least in O(n) time (lower bound on time).