Especially given the emphasis on YAGNI, you don’t need a UUID primary key, and all of its problems they bring for B+trees (that thing RDBMS is built on), nor do you need the collision resistance of SHA256 - the odds of you creating a dupe job hash with MD5 are vanishingly small.
As to the actual topic, it’s fine IFF you carefully monitor for accumulating dead tuples, and adjust auto-vacuum for that table as necessary. While not something you’d run into at the start, at a modest scale you may start to see issues. May. You may also opt to switch to Redis or something else before that point anyway.
EDIT: if you choose ULID, UUIDv7, or some other k-sortable key, the problem isn’t nearly as bad, but you still don’t need it in this situation. Save yourself 8 bytes per key.