Having transactions is quite handy.
https://wiki.postgresql.org/wiki/SkyTools
I did a few talks on this at Sydpy as I used it at work quite a bit. It's handy when you already have postgresql running well and supported.
This said, I'd use a dedicated queue these days. Anything but RabbitMQ.
It works great until it doesn't, and the way it breaks puts you in a state that's very difficult to recover from. And if your excuse for using a database as a queue was that you were already running a database, that cuts both ways: congratulations, your queue mess has now brought down your primary datastore too.
Just don't put your queue tables/logic in the same DB instance as your datastore. There are still a lot of benefits to using the same tech even if you have segregated instances.